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Beilstein J. Org. Chem. 2015, 11, 2577–2583, doi:10.3762/bjoc.11.277
Graphical Abstract
Scheme 1: Diastereodivergent cascade Michael/Michael reaction using catalysts with the same absolute chiralit...
Scheme 2: Diastereodivergent enantioselective Michael reaction using ethyl 2-nitropropanoate and β-nitrostyre...
Figure 1: ORTEP diagrams for anti-3a and syn-3o respectively.
Scheme 3: Proposed models to explain the stereochemical outcome of the reaction.